As much as i know: no
But you can make a dummy autocast spell and order a dummy unit (position should be the same as the casting unit) to cast the needed Spell.
Try make the autocast ability channel for 2 seconds then for triggering create the dummy and find an random enemy unit to cast Chain Lightning on then remove the unit.
I made an example map, well, it contains JASS, but it's only cause i like JASS more than GUI and i hope you understand it
else i can make an GUI Version too, but not today, it's already 23:40.